To aid in the unit operation calculations, the Excel Unit-Operation Add-In provides a number of functions that you can use. Most of them provide access to thermodynamic property and equilibrium calculations.
Nearly all functions require at least one feed or product port to be connected. The unit operation has access to the thermodynamic system of the simulation environment through the streams connected to the ports. The Excel unit operation assumes that all connected ports serve the same thermodynamic; the thermodynamics system that is used for the calculations corresponds to that of the first connected port.
A quick reference of the available functions is given on the control sheet. Tips to work with functions:

General purpose functions
Thermo-dynamic functions
Obtaining units-of-measure